Microsoft just launched the NGO Connection "to provide nongovernmental organizations (NGOs) a place to go to learn how to use technology more effectively and to access the resources Microsoft and its partners offer. The website provides free or discounted software applications, training and certification information, and NGO discussion forums. The goal of the website is to help NGOs achieve their organizational goals more efficiently. Visit the website listed above to learn more about this new online resource."
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You can learn more about Microsoft's own giving program here: